Well, get a head texture from Google, the Art Section, buy one, or make one yourself. Then , go to your deactivated/activated (where ever your head item is located), press 'edit,' then upload the image.
About the find one on google. try to avoid watermarked heads, usually this means that the artist didn't want them used for free so just a heads up. however you can find a lot of free head texture threads out there and even free set textures.
Life's not a waste of time and time's not a waste of life so let's stop wasting time, get wasted and have the time of our lives - Mr Worldwide 3:18