You have done a great work on the eyes, the left iris made a difference in you design.
The anger look can be more intense yet,
put the eyebrows(close to the middle) with more anger, so more low, as the other side(going aways from the middle) goes up.
with two more lines on the nose bridge between the eyes, one of each side to express anger, it can work better.
it still looks flat.
shading is not necessary, but gives it a totally different look.