I can see this work somehow by using the left stick as a dial to switch between joints in a circular fashion. The buttons are for holding, relaxing, extending and contracting. Maybe then the triggers as left grab right grab, and the bumpers as hold all and relax all. Start will be the menu button obviously, and the right stick is used to look around. Not sure how to get the camera closer and further away.
It might work. But I doubt it'll be convenient.